The correct option is C c) SOCl2/ Pyridine
Answer: c
Explanation: The best method of preparation of alkyl halides is a reaction of an alcohol with SOCl2/ Pyridine because by-products formed in the reaction are SO2 and HCl which are in gaseous form and escape into the atmosphere leaving behind pure alkyl chlorides.
CH3CH2−OH + SOCl2 → CH3CH2−Cl + SO2↑ + HCl↑