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Question

Which of the following reactant gives the best method of preparation of alkyl halides when reacts with alcohol?

A
a) Zn/HCl
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B
b) PCl5
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C
c) SOCl2/ Pyridine
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D
d) PCl3
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Solution

The correct option is C c) SOCl2/ Pyridine
Answer: c
Explanation: The best method of preparation of alkyl halides is a reaction of an alcohol with SOCl2/ Pyridine because by-products formed in the reaction are SO2 and HCl which are in gaseous form and escape into the atmosphere leaving behind pure alkyl chlorides.
CH3CH2OH + SOCl2CH3CH2Cl + SO2 + HCl

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