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Question

Which of the following reaction involves diazonium salt as an intermediate?

A
C2H5NH2+HNO2NaNO2−−−HCl[C2H5N+2Cl]H2OC2H5OH+N2
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B
C2H5NH2+CH3CHOH+CH3CH=NCH2CH3+H2O
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C
C2H5NH2+CHCl3+3KOHwarm−−CH3CH2NC+3KCl+3H2O
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D
C2H5NH2+C6H5COClaqNaOH−−−−−C2H5NHCOC6H5+HCl
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Solution

The correct option is A C2H5NH2+HNO2NaNO2−−−HCl[C2H5N+2Cl]H2OC2H5OH+N2
The following reaction involves diazonium salt as an intermediate.
C2H5NH2+HNO2NaNO2−−−HCl[C2H5N+2Cl]H2OC2H5OH+N2
The diazonium salt is [C2H5N+2Cl]

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