Which of the following reaction represents Schmidt reaction?

C_{2} H_{5} C O O H + H N_{3} c o n c . H_{2} S O_{4} - ------- \to C_{2} H_{5} N H_{2} + C O_{2} + N_{2}

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C_{2} H_{5} C O N_{3} h e a t - - \to C_{2} H_{5} N C O H_{2} O - - \to C_{2} H_{5} N H_{2}

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C H_{3} - C H_{2} - N = C = O + 2 K O H \to C_{2} H_{5} N H_{2} + K_{2} C O_{3}

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C H_{3} C H O + N H_{3} + H_{2} N i 150^{0} C 300 a t m - ---------- \to C_{2} H_{5} N H_{2} + H_{2} O

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Solution

The correct option is A $C_{2} H_{5} C O O H + H N_{3} c o n c . H_{2} S O_{4} - ------- \to C_{2} H_{5} N H_{2} + C O_{2} + N_{2}$
The following reaction represents Schmidt reaction.
$C_{2} H_{5} C O O H + H N_{3} c o n c . H_{2} S O_{4} - ------- \to C_{2} H_{5} N H_{2} + C O_{2} + N_{2}$
In Schmidt reaction, carboxylic acids react with hydrazoic acid in presence of conc. sulphuric acid to form amine directly.

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Similar questions

Which of the following is the example of SN² reaction

[CPMT 1999]

A, B

C

2 C H_{3} - C H_{2} - O H H^{+} - -- \to 413 K C H_{3} - C H_{2} - O - C H_{2} - C H_{3} + H_{2} O

(A)

{C H}_{3} {C H}_{2} - N = N - {C H}_{2} {C H}_{3} h e a t - - \to (A) + N_{2}

C H_{3} - C H_{3} | C = O

C H_{2} = P P h_{3} D M S O - --- \to C H_{3} - C H_{3} | C = C H_{2} + P h_{3} P = O

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