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Question

Which of the following reactions does not give benzaldehyde?

A
Rosenmund reaction
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B
Etard reaction
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C
Gatterman-Koch reaction
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D
Friedel craft acylation reaction
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Solution

The correct option is D Friedel craft acylation reaction
Friedel-Crafts acylation of benzene produces an aromatic ketone and not benzaldehyde. Benzene on Gatterman-Koch reaction gives benzaldehyde, so does toluene on Etard reaction. Rosenmund reaction also gives benzaldehyde but from benzoyl chloride.
Etard ReactionRosendmund ReactionGatterman-Koch Reaction

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