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Question

Which of the following reactions have Kp<Kc?

A
H2(g)+I2(g)2HI(g)
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B
CO(g)+Cl2(g)COCl2(g)
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C
2BrCl(g)Br2(g)+Cl2(g)
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D
N2(g)+3H2(g)2NH3(g)
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Solution

The correct options are
B CO(g)+Cl2(g)COCl2(g)
D N2(g)+3H2(g)2NH3(g)
The following reactions have Kp<Kc.
CO(g)+Cl2(g)COCl2(g) Δn=1(1+1)=1
N2(g)+3H2(g)2NH3(g) Δn=2(1+3)=2
For such reactions Δn<0
Kp=Kc(RT)Δn

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