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Question

Which of the following reactions is/are disproportionation reaction(s)?

A
Cl2+2OHCl+ClO+H2O
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B
2HCuCl2Cu+Cu2++4Cl+2H
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C
HCHO+OHCH3OH+HCOO
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D
MgCO3MgO+CO2
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Solution

The correct options are
A Cl2+2OHCl+ClO+H2O
B 2HCuCl2Cu+Cu2++4Cl+2H
C HCHO+OHCH3OH+HCOO
a. 2e+Cl22Cl (Reduction)
2ClO+2e (Oxidation)
Hence, it is a disproportionation reaction.
b. It is also a disproportionation reaction.
[+1H+1Cu1×2Cl2]
e+Cu1+Cu (Reduction)
Cu1+Cu2++e (Oxidation)
c. It is also a disproportionation reaction.
HCHO is oxidised to HCOO and reduced to CH3OH.
d. It is not, sinc,e the oxidation state of Mg is +2 in both reactant and product. Similarly, the oxidation states of C and O are +4 and -2 in both reactant and product.

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