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Question

Which of the following reactions is disproportionation reaction ?
(a) 2Cu+Cu2++Cu(b) 3MnO24+4H+2MnO4+MnO2+2H2O(c) 2KMnO4K2MnO4+MnO2+O2(d) 2MnO4+3Mn2++2H2O5MnO2+4H+
Select the correct option from the following:

A
(a) and (d) only
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B
(a) and (b) only
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C
(a), (b) and (c)
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D
(a), (c) and (d)
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Solution

The correct option is B (a) and (b) only
Disproportionation reaction are the reactions in which the same element/compound get oxidized and reduced simultaneously.
Since, I and II reactions are as follows:
2Cu++2Cu2++0Cu
And
3+6MnO24+4H+2+7MnO4++4MnO2+2H2O
Other two reactions are not disproportionation reaction. They are comproportionation reactions.
Thus, option (c) is correct.

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