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Question

Which of the following reactions is not a part of Solvay's process for preparation of sodium carbonate?

A
2NH3+H2O+CO2(NH4)2CO3
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B
(NH4)2CO3+H2O+CO22NH4HCO3
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C
2NH4HCO3(NH4)2CO3+H2O+CO2
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D
NH4HCO3+NaClNH4Cl+NaHCO3
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Solution

The correct option is C 2NH4HCO3(NH4)2CO3+H2O+CO2
The following reaction in solvay's process took place:
CaCO3CaO+CO2
2NH3+CO2+H2O(NH4)2CO3
(NH4)2CO3+CO2+H2O2NH4HCO3
NH4HCO3+NaClNaHCO3+NH4Cl
2NaHCO3Na2CO3+H2O+CO2
Thus the reaction given in option C is not a part of Solvay's process for preparation of sodium carbonate.

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