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Question

Which of the following reactions is not possible?

A
ROH+NaBrRBr+NaOH
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B
ROH+HBrRBr+H2O
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C
Both reactions are possible
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D
Both reactions are not possible
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Solution

The correct option is C ROH+NaBrRBr+NaOH
OH is not a good leaving group so attach of Br do not take place easily. This reaction is possible in the presence of acids like HCl,H2SO4.

OH is not a good leaving group as it is a strong base. If you add H+

ROH+H+ROH+2

Now H2O is a good leaving group so now it can be replaced by Br.

Hence option A is correct.


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