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Question

Which of the following reactions is not taking place in Blast furnace during metallurgy of iron between the temperature range of 500-800 K?

A
FeO+COFe+CO2
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B
3Fe2O3+CO2Fe3O4+4CO2
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C
Fe3O4+4CO3Fe+4CO2
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D
Fe2O3+CO2Fe+CO2
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Solution

The correct option is A FeO+COFe+CO2
After concentration, the mixture of oxide ores of iron (Fe2O3,Fe3O4) is subjected to calcination/roasting to remove water, to decompose carbonates and to oxidise sulphides.
Various reactions involved in Blast furnace are at 500-800 K are-
Fe2O3 is first reduced to Fe3O4 and then to FeO
3Fe2O3+CO2Fe3O4+CO2
Fe3O4+4CO2Fe+4CO2
Fe2O3+CO2FeO+CO2

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