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Question

Which of the following reactions of benzene proves the presence of three carbon-carbon double bonds in it?

A
Formation of a triozonide with ozone
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B
Hydrogenation of benzene to cyclohexane
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C
Formation of C6H6Cl6 by addition of chlorine
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D
Formation of nitobenzene on heating benzene with a mixture of concentrated nitric acid and suphuric acid
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Solution

The correct options are
A Formation of a triozonide with ozone
B Hydrogenation of benzene to cyclohexane
C Formation of C6H6Cl6 by addition of chlorine
Formation of a triozonide with ozone indicates that three double bonds are present. Each double bond forms an ozonide.
Hydrogenation of 1 mole of benzene to cyclohexane requires 3 moles of hydrogen. This also indicates the presence of 3 double bonds.
To one mole of benzene, 3 moles of chlorine are added to form 1,2,3,4,5,6-hexachlorocyclohexane C6H6Cl6. This also indicates the presence of 3 double bonds.

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