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Question

Which of the following reactions of glucose can be explained only by its cyclic structure?

A
Glucose forms pentaacetate
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B
Glucose reacts with hydroxylamine to form an oxime
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C
Pentaacetate of glucose does not react with hydroxylamine
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D
Glucose is oxidised by nitric acid to gluconic acid
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Solution

The correct option is D Pentaacetate of glucose does not react with hydroxylamine
Pentaacetate of glucose does not react with hydroxylamine
The pentaacetate of glucose does not react with hydroxylamine indicating the absence of free -CHO group. This property of glucose can be explained only by its cyclic structure.

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