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Question

Which of the following reactions will give a Hoffmann product as the major product?

A
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B
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C
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D
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Solution

The correct options are
C
D
(a) Saytzeff product is obtained due to the abstraction of the most acidic proton at benzylic position.

(b) Saytzeff product is obtained due to the abstraction of the most acidic proton at benzylic position.

(c) Hoffmann product obtained as the bulkier base abstracts a proton from the less hindered side.

(d) Hoffmann product is formed as the extended conjugation leads to a more stable product.


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