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Question

Which of the following reactions will yield 2,2-dibromopropane?

A
CH3CCH + 2HBr
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B
CH3CH=CHBr + HBr
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C
CHCH + 2HBr
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D
CH3CH=CH2 + HBr
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Solution

The correct option is A CH3CCH + 2HBr
When 2 moles of HBr add to 1 mole of propyne, 2,2-dibromopropane is obtained. Br is added to C atom having least number of H atoms.

CH3CCHHBr−−CH3C(Br)=CH2HBr−−CH3C(Br2)CH32,2 dibromopropane

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