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Question

Which of the following reagent will react with ethyl amine followed by thermal decomposition with mercuric chloride to form a compound with characteristic smell like mustard oil.

A
CS2
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B
SO2
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C
H2S
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D
Na2S
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Solution

The correct option is B CS2
Carbon disulphide will react with ethyl amine followed by thermal decomposition with mercuric chloride to form ethyl isothiocyanate with characteristic smell like mustard oil.
CH3CH2NH2+S=C=SΔCH3CH2NHC(S)SHHgCl2−−−ΔCH3CH2N=C=S+HgS+2HCl

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