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Reductions Involving Aldehydes or Ketones

Which of the ...

Question

Which of the following reagents converts both acetaldehyde and acetone to alkanes?

A

N i / H_{2}

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B

L i A l H_{4}

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C

I_{2} / N a O H

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D

Z n - H g / C o n c . H C l

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Solution

The correct option is D $Z n - H g / C o n c . H C l$
$Z n - H g / C o n c . H C l$ reacts with carbonyl compounds to give alkanes as a product ( $Clemmensen reduction$ ).
It can react with both aldehydes as well as ketones.

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Q. Match the column I with column II and mark the appropriate choice.

	Column I		Column II
(A)	Clemmensen reduction	(i)	$C o n c . K O H$
(B)	Rosenmund reduction	(ii)	$Z n / H g + c o n c . H C l$
(C)	Iodoform reaction	(iii)	$H_{2} / P d - B a S O_{4}$
(D)	Cannizzaro	(iv)	$N a O H + I_{2}$

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