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Question

Which of the following reagents may be used to distinguish between ethene and ethyne ?

A
Ammoniacal AgNO3
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B
KMnO4
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C
Br2/CCl4
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D
AlCl3
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Solution

The correct option is A Ammoniacal AgNO3
Ammonical silver nitrate solution(Tollen's reagent) is used to distinguish between ethene and ethyne.
Ethyne + tollens reagent --------> silver acetylide (white ppt) + NH3 + H2O
Ethene + tollens reagent ---------> no reaction

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