Which of the following regents would carry out the following transformation? $(D =^{2} H)$

N a B D_{4}

C H_{3} O H

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L i A l H_{4}

, then

D_{2} O

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N a B D_{4}

C H_{3} O D

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L i A l D_{4}

, then

D_{2} O

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Solution

The correct option is A $N a B D_{4}$ in $C H_{3} O H$
The $D^{⊝}$ nucleophile in $N a B D_{4}$ attack the electrophilic carbonyl atom of ketone. The hydrogen for $O^{⊝}$ is taken from solvent.

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Similar questions

1 -

1 - D -

D_{2} O

C H_{3} C H_{2} C H = C H_{2} 1. H g (O A c)_{2} . H_{2} O - --------- \to 2. N a B D_{4}

D_{2} O

D_{2} O

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