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Question

Which of the following relation is correct for the reaction PCl5(g)PCl3(g)+Cl2(g)

A
ΔH=ΔE
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B
ΔH>ΔE
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C
ΔH<ΔE
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D
ΔH=ΔERT
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Solution

The correct option is B ΔH>ΔE
PCl5(g)PCl3(g)+Cl2(g)
Here Δng=1
The relation between ΔH and ΔE is given by
ΔH=ΔE+ΔngRTΔH=ΔE+RT
ΔH>ΔE

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