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Question

Which of the following represent(s) the correct order of electron affinities?

A
F > Cl > Br > I
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B
C < N < Cl < F
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C
N < C < O < F
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D
C < Si < P < N
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Solution

The correct options are
C N < C < O < F
D C < Si < P < N
Generally, the electron affinity values of 3rd period elements are higher than the elements of the 2nd period of the same group because of less interelectronic repulsions. Atomic size, nuclear charge, and electrons configurations also affect the electron affinity.
Electron gain enthalpies in kJmol1 are: C=121,Si=134;P=74;NO,O=142,F=328

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