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Question

Which of the following represents the correct IUPAC name of the compound CH2=CHCH2Cl?

A
Allyl chloride
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B
1-Chloro-3-propene
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C
3-Chloro-1-propene
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D
Vinyl chloride
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Solution

The correct option is C 3-Chloro-1-propene
Following steps are followed in naming the compound; CH2=CHCH2Cl
i) The parent chain consists of 3 carbon atoms, thus the root word; -prop is used.
ii) It is an unsaturated hydrocarbon with a double bond, thus the suffix; -ene is used.
iii) Chloro is used as a prefix for the halogen(chlorine) present as a substituent.
iii) Numbering is done from left to right as a double bond is assigned the lowest number.

Thus the name of the compound is; 3-Chloro-1-propene.

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