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Question

Which of the following represents the correct order of increasing pKa values of the given acids?

A
HClO4<HNO3<H2CO3<B(OH)3
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B
HNO3<HClO4<B(OH)3<H2CO3
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C
B(OH)3<H2CO3<HClO4<HNO3
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D
HClO4<HNO3<B(OH)3<H2CO3
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Solution

The correct option is A HClO4<HNO3<H2CO3<B(OH)3
As we know,
acidic strength of acids as
HClO4>HNO3>H2CO3>B(OH)3
+7 +5 +4
and as we know,
more stronger acid have lower value of pKa so
pKa order
HClO4<HNO3<H2CO3<B(OH)3

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