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Question

Which of the following salt will have the same value of Van’t Hoff factor as that of Ba3(PO4)2? (Assume 100% dissociation)

A
Al2(SO4)3
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B
K4[Fe(CN)6]
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C
Both (A) and (B)
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D
None of these
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Solution

The correct option is C Both (A) and (B)
i for Ba3(PO4)2 is 5 and i for Al2(SO4)3 and K4[Fe(CN)6]is also 5
Al2(SO4)32Al+3+3SO24
K4[Fe(CN)6]=4K++[Fe(CN)6]4

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