The correct option is B Blue vitriol
The water of crystallisation denotes the number of water molecules present in the crystal structure of salts.
The table given below is showing the chemical formula of the given chemical compounds.
Chemical compoundFormulaNo. of water moleculesBaking sodaNaHCO30Blue vitriolCuSO4.5H2O5Washing soda Na2CO3.10H2O 10Gypsum CaSO4.2H2O2
So from the table, it is clear that only baking soda does not contain water of crystallisation.