The correct option is B Ti, Co, Cu
The first transition series or 3d series corresponding to the filling of 3d sublevel consists of the following 10 elements of the 4th period: Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu and Zn. Hence Vanandium (V) belongs to first transition series.
Hence, option (a) and (b) are correct.