The correct option is C P,S,Cl
All the elements in a particular group have the same number of valence electrons and hence possess similar chemical properties. Among the given options:
a) F,Cl,Br are classified as halogens and have 7 valence electrons. Thus they belong to group 17 of the periodic table.
b) Na,K,Rb are classified as alkali metals and have 1 valence electron. These elements are present in group 1 of the periodic table.
c) Phosphorus has 5 valence electrons and belongs to group 15.
Sulphur has 6 valence electrons and belongs to group 16.
Chlorine has 7 valence electrons and thus belongs to group 17 in the modern periodic table.
d) C,Si,Ge belong to the carbon family and have 4 valence electrons, and they are present in group 14 of the periodic table.