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Question

Which of the following sets of molecules have different shape but same hybridisation of the central atoms?

A
NH3, H2O
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B
H2S, SO2
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C
Ni(CO)4, [NiCl4]2
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D
SF4, PCl5
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Solution

The correct options are
A NH3, H2O
D SF4, PCl5
NH3 N atom sp3hybridised -Bipyramidal
H2O O atom sp3hybridised -V-shaped
H2S S atom sp3hybridised -Bent
SO2 S atom sp2hybridised -Bent
Ni(CO)4 Ni atom sp3hybridised -Tetrahedral
[NiCl4]2 Ni atom sp3hybridised -Tetrahedral
SF4 S atom sp3dhybridised -see-saw
PCl5 P atom sp3hybridised -Bipyramidal


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