Which of the following shows maximum number of isomers?

[C o (N H_{3})_{4} C l_{2}]

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[N i (e n) (N H_{3})_{4}]^{2 +}

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[N i (C_{2} O_{4}) (e n)_{2}]^{2 -}

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[C r (S C N)_{2} (N H_{3})_{4}]^{+}

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Solution

The correct option is B $[C r (S C N)_{2} (N H_{3})_{4}]^{+}$
$[C r (S C N)_{2} (N H_{3})_{4}]^{+}$ shows maximum number of isomers. It shows geometrical (cis trans) isomerism as well as linkage isomerism. $S C N^{-}$ is ambidentate ligand and can coordinate through either S or N atom.

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[C o (N H_{3})_{4} C l_{2}]^{+}

[C o (N H_{3})_{4} C l_{2}]

[C o (N H_{3}) C l (e n)_{2}]^{2 +}

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