Which of the following solution has the lowest freezing point temperature?
Since all of them have the same molar concentration, compound breaks up into the most individual particles.
MgCl2→Mg2++Cl1−+Cl1− (3 particles)
HClO4→H1++ClO1−4(2 particles)
NH4OH→NH1+4+OH1−(2 particles)
KOH→K1++OH1− (2 particles)
LiNO3→Li1++NO1−3 (2 particles)
Therefore ans. is MgCl2.