Which of the following solutions shows negative deviation from Raoult's law?

Acetone and chloroform

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Benzene and toluene

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Acetone and carbon disulphide

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Ethyl alcohol and cyclohexane

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Solution

The correct option is A
Acetone and chloroform

On mixing acetone and chloroform, hydrogen bond is formed between them. Due to this vapour pressure of the solution formed by them decreases. Hence solution shows negative deviation from Raoult's law

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