Which of the following solutions when added to 1L of a 0.1MCH3COOH solution will cause no change in either the degree of dissociation of CH3COOH or the pH of the solution. Ka=1.8×104 for CH3COOH?
A
3mMHCOOH(Ka=6×104)
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B
0.1MCH3COONa
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C
1.34mMHCl
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D
0.1MCH3COOH
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Solution
The correct option is A3mMHCOOH(Ka=6×104) Addition of CH3COOH and HCl will change the pH. Adding the CH3COONa will form a buffer solution and hence change the pH. Here, addition of HCOOH will not change degree of dissociation or pH of the solution.