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Question

Which of the following species are not known?

A
[SiCl6]2
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B
[CF6]2
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C
[PbCl6]2
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D
[SiF6]2
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Solution

The correct options are
A [SiCl6]2
C [CF6]2
In (SiCl6)2, the chlorine is much larger than fluorine which does not allow the six chlorines to surround the silicon due to repulsion between chlorine atoms.
Silicon cannot accomodate 6 chlorines around it.
Carbon doesn't form (CF6)2 because it does not have any vacant d-orbitals of lower energy and hence it is unable to accept lone pair of electrons in order to form (CF6)2

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