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Question

Which of the following species exhibits diamagnetic behaviour?

A
NO
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B
O22
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C
O+2
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D
O2
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Solution

The correct option is D O22
O22 all the molecular orbitals are completely filled except σ2pz and paired electrons. Therefore it is diamagnetic.

NO has 15 electrons, species having odd electrons are always paramagnetic.

O+2 has 15 electrons.

O2 molecule has 2 unpaired electrons as per MOT making it paramagnetic.

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