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Question

Which of the following species have only one type of bond length?

A
AsF3
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B
AsF4
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C
AsF+4
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D
AsF6
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Solution

The correct options are
A AsF3
C AsF+4
D AsF6
A) AsF3 is trigonal pyramidal, where all F atoms are present in axial position. So, all bond lengths are equal.
B) The shape of AsF4 is See-saw. So, two axial bonds are longer than the two equitorial bonds.
C) AsF+4 is tetrahedral in shape. All bond lengths are equal.
d) AsF6 is octahedral in shape. All bond lengths are equal to each other in a octahedral.

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