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Question

Which of the following species will not exhibit disproportionation reaction?

A
ClO
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B
ClO2
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C
ClO3
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D
ClO4
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Solution

The correct option is B ClO4
A substance can exhibit disproportionation reaction if it can increase as well as decrease its oxidation state.
Maximum oxidation number of Cl is +7 and minimum oxidation number is 1.
In ClO, chlorine is present in +1 oxidation state so it can increase as well as decrease its oxidation state.
In ClO2, chlorine is present in +3 oxidation state so it can increase as well as decrease its oxidation state.
In ClO3, chlorine is present in +5 oxidation state so it can increase as well as decrease its oxidation state.
In ClO4, chlorine is present in +7 oxidation state so it cannot increase its oxidation state.
So only ClO4 will not exhibit disproportionation reaction.

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