Which of the following statement are true regarding the log K vs. 1/T plot shown in the given diagram?
A
Plot P shows that the energy of activation is independent of temperature
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B
Plot Q describes the behaviour of temperature dependence of energy of activation
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C
Arrhenius behaviour is described by P
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D
The slope of curve P gives the value −EaR
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Solution
The correct options are A Arrhenius behaviour is described by P B Plot P shows that the energy of activation is independent of temperature C Plot Q describes the behaviour of temperature dependence of energy of activation D The slope of curve P gives the value −EaR Arrhenius equation is given as below:
k=Ae−Ea/RT
logk=logA−Ea/RT
So, the Arrhenius behaviour is described by P and the slope of curve P gives the value −Ea/R.
Here, the energy of activation is independent of temperature.
While plot Q describes the behaviour of temperature dependence of energy of activation.