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Question

Which of the following statement is correct regarding the rate of hydrolysis of the compounds (A) and (B) by SN1 reaction ?
989685_048d2358232842efa9ee8e7e84f14f5c.png

A
A reacts faster than B
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B
B reacts faster than A
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C
Both A and B react at the same rate
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D
Neither A nor b reacts
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Solution

The correct option is D B reacts faster than A
The formation of cation is readily favorable in 'b' due to presence of oxygen. The carbocation formed will be resonance stabilized by lone pair electrons of oxygen as given below.
1056534_989685_ans_b56d237f09014f12986fdeb152396c2a.PNG

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