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Question

Which of the following statement is false:

A
S for N2(g)2N(g) is negative
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B
Gsystem is always zero for a reversible process in a closed system
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C
Go for an ideal gas is a function of temperature and pressure
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D
Entropy of a isolated system is always maximized at equilibrium
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Solution

The correct option is C Go for an ideal gas is a function of temperature and pressure

As no. of moles of gas increasing, so entropy would increase.
Hence, S>0


As ΔG is 0 only at equilibrium.

As we know at equilibrium ΔG=0 so,
Go=RT ln K
Clearly, ΔG is only function of Temperature


From Principle of maximum entropy which states that,
The entropy of an isolated system (closed system with fixed internal energy) is maximum at equilibrium.


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