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Question

Which of the following statement is true about NO2 and ClO2 ?

A
Both are paramagnetic.
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B
Both have a bent structure.
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C
On cooling,both undergoes dimerisation.
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D
In both oxides, the central atom has an oxidation state is +4.
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Solution

The correct options are
A Both are paramagnetic.
B Both have a bent structure.
D In both oxides, the central atom has an oxidation state is +4.
From figure it can be seen that both have a bent structure.
In both oxides, the central atom has an oxidation state is +4.

As it has odd number of electrons both are paramagnetic in nature.

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