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Question

Which of the following statement(s) is/are correct when a solid mixture of KCl and K2Cr2O7 is gently warmed with conc. H2SO4?

A
A deep red vapour is evolved
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B
The vapour when passed into `NaOH` solution gives a yellow solution
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C
Chlorine gas is evolved
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D
Chromyl chloride is formed
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Solution

The correct options are
A A deep red vapour is evolved
B The vapour when passed into `NaOH` solution gives a yellow solution
D Chromyl chloride is formed
When a solid mixture of KCl and K2Cr2O7 is heated with conc. H2SO4, the products obtained are:

4KCl+K2Cr2O7+6H2SO42CrO2Cl2(Red vapour)+6KHSO4+3H2O

CrO2Cl2+4NaOHNa2CrO4(Yellow solution)+2NaCl+2H2O

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