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Question

Which of the following statement(s) would be incorrect about the following compound?

A
All three CN bonds are of the same length
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B
C1N and C3N bonds are of the same length but shorter than the C5N bond
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C
C1N and C5N bonds are of the same length but longer than the C3N bond
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D
C1N and C5N bonds are of the same length but both are shorter than the C3N bond
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Solution

The correct option is D C1N and C5N bonds are of the same length but both are shorter than the C3N bond
Due to the steric hinderance of three groups, the NO2 group go out of the plane with benzene ring and so conjugation of NO2 group with benzene is slightly diminished. So, C1N and C5N bonds are of same length but longer than C3N bond

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