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Question

Which of the following statements about regioselectivity of elimination reactions is not correct?

A
More substituted and more stable alkenes are formed preferentially by both E1 and E2 mechanisms.
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B
substrates with a poorer nucleophile tend to give the less substituted alkenes.
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C
Sterically hindered, bulky bases give the less substituted alkenes.
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D
Reactions by the E1 mechanism are generally less regioselective than those by the E2 mechanism.
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Solution

The correct option is D Reactions by the E1 mechanism are generally less regioselective than those by the E2 mechanism.
E1 reactions are regioselective and form two products depending on the position of double bond and base they form major and minor products. The major product is called the saytzef product, a more substituted alkene and the minor product is Hofmann product it is less substituted alkene as shown in given example.

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