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Question

Which of the following statements, about the advantage of roasting of sulphide ore before reduction is not true?

<!--td {border: 1px solid #ccc;}br {mso-data-placement:same-cell;}--> AIPMT 2007

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Solution

The standard free energies of formation ΔfG0 of most of the sulphides are greater than those of CS2 and H2S. Hence, neither carbon nor hydrogen can reduce metal sulphides to metal. The standard free energies of formation of oxides are much lower than those of SO2. Therefore, oxidation of metal sulphides to metal oxides is thermodynamically favourable. Hence sulphide ore is roasted to the oxide before reduction.

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