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Question

Which of the following statements are applicable to a balanced chemical equation of an elementary reaction?
(a) Order is same as molecularity
(b) Order is less than the molecularity
(c) order is greater than the molecularity
(d) Molecularity can never be zero

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Solution

Answers: (a), and (d)
For a balanced chemical equation of an elementary reaction, the order is same as molecularity and molecularity can never be zero. If molecularity of a reaction is considered to be zero it means that no reactant is going to transform into a product. Consider a chemical reaction.
2NO(g)+O2(g)2NO2(g)
Differential rate law expression can be written as
dRdt=k[NO]2[O2]
Here, molecularity = 3, order = 3


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