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Question

Which of the following statements are correct regarding the hardness of water?

A
The temporary hardness of water is due to the presence of bicarbonates of Ca and Mg
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B
The temporary hardness of water is due to the presence of sulphates of Na and Mg.
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C
The permanent hardness of water is due to the presence of bicarbonates of Na and Mg.
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D
Permanent hardness is due to presence of soluble chlorides and sulphates of Ca and Mg.
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Solution

The correct options are
A The temporary hardness of water is due to the presence of bicarbonates of Ca and Mg
D Permanent hardness is due to presence of soluble chlorides and sulphates of Ca and Mg.
Types of Hardness :
1. Temporary hardness
2. Permanent hardness
Temporary hardness
Temporary hardness is due to the presence of soluble bicarbonates
of Ca and Mg.
Examples: Ca(HCO3)2 and Mg(HCO3)2
Boiling :
Mg(HCO3)2(aq)ΔMgCO3(s)+CO2(g)+H2O(l)
Ca(HCO3)2(aq)ΔCaCO3(s)+CO2(g)+H2O(l)
Permanent hardness :
Permanent hardness is due to presence of soluble chlorides and sulphates of Mg and Ca.
Example: CaCl2,CaSO4,MgCl2,MgSO4
This type of hardness is referred to as "permanent" because unlike temporary hardness, it cannot be removed by simple methods.

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