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Question

Which of the following statements are true?

A
Only type of interactions between particles of noble gases are due to weak dispersion forces.
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B
Ionization enthalpy of molecular oxygen is very close to that of xenon.
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C
Xenon fluorides are not reactive.
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D
Hydrolysis of XeF6 is a redox reaction.
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Solution

The correct option is B Ionization enthalpy of molecular oxygen is very close to that of xenon.
Analyzing the Options

Option (A):

All noble gases have weak intermolecular forces i.e., dispersion or Vander Waals forces.

As noble gases exist as monoatomic gases, they can have only weak dispersion forces between them.

Option (B):

The Ionization energy of O2 is 1170 kJ/mol and ionization energy of Xe is 1170 kJ/mol as observed by Neil Bartlett and they are nearly the same.

This particular property was actually used to form the first compound of Xe which was Xe+PtF6

Option (C):

Hydrolsis reaction of XeF6 is XeF6+3H2O XeO3 + 6HF
The Oxidation state of Xe in XeF6 and XeO3 is same i.e., +6.

Since the oxidation number of Xe remains same, the given reaction is not a redox reaction.

Option (D):

Xe fluorides are XeF2,XeF4 and XeF6.
All are powerful fluorinating agents.
They can also easily get hydrolysed even by traces of water.

2XeF2+2H2O 2Xe+ 4HF+O2
Therefore, Xenon fluorides are highly reactive in nature.

Hence, options (A) & (B) are the correct options.

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