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Question

Which of the following statements are true?


(i) Order and molecularity may be equal for some reactions.
(ii) Order can be a fraction.
(iii) molecularity can be a fraction.
(iv) molecularity is always a whole number.

A
i, ii, iii
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B
iii, iv
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C
i, ii, iv
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D
ii, iv
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Solution

The correct option is A i, ii, iv
In some reaction molecularity (theoretical value) may be equal to the order of a reaction (experimental value).
The order of a reaction may be fractional, zero, positive or negative.
Molecularity can never be fractional.

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