(i) Order and molecularity may be equal for some reactions. (ii) Order can be a fraction. (iii) molecularity can be a fraction. (iv) molecularity is always a whole number.
A
i, ii, iii
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B
iii, iv
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C
i, ii, iv
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D
ii, iv
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Solution
The correct option is A i, ii, iv In some reaction molecularity (theoretical value) may be equal to the order of a reaction (experimental value). The order of a reaction may be fractional, zero, positive or negative. Molecularity can never be fractional.