Which of the following statements best explains the difference in melting point between MgO(2852∘C) and NaF(1819∘C)?
A
Sodium, being an alkali metal, is more reactive magnesium, an alkaline earth metal.
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B
Magnesium and oxygen have higher charge values and therefore have greater Coulombic attractions.
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C
Fluorine is more electronegative than oxygen.
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D
The oxide ion is larger than the fluoride ion.
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Solution
The correct option is D Magnesium and oxygen have higher charge values and therefore have greater Coulombic attractions.
Coulumbic attraction between 2 ions=kq1q2r2 i.e., directly proportional to charge. Mg2+ and O2− have higher charge values hence have greater attraction force hence have higher melting point. Thus correct option is B.