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Question

Which of the following statements illustrates the law of multiple proportions?

A
An element forms two oxides, XO and XO2 containing 50% and 60% oxygen respectively. The ratio of masses of oxygen which combines with 1 g of element is 2:3
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B
Hydrogen sulphide contains 5.89% hydrogen, water contains 11.1% hydrogen and sulphur dioxide contains 50% oxygen.
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C
3.47 g of BaCl2 reacts with 2.36 g of Na2SO4 to give 3.88 g of BaSO4 and 1.95 g of NaCl.
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D
20 mL of ammonia gives 10 volumes of N2 and 30 volumes of H2 at constant temperature and pressure
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Solution

The correct option is A An element forms two oxides, XO and XO2 containing 50% and 60% oxygen respectively. The ratio of masses of oxygen which combines with 1 g of element is 2:3
Law of multiple proportions states that when two elements combine to form two or more compounds, the masses of one element which combine with the fixed mass of another element, will always be in ratio of whole numbers.
The statement is :
An element forms two oxides XO and XO2 containing 50% and 60% of oxygen respectively. The ratio of masses of O2 which combine with 1g of element of 2:3.

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